文献类型：会议

作　　者：Xin Huang Chunling Fu Shengming Ma

作者单位：浙江大学理学部化学系

基　　金：国家重点基础研究发展计划(2011CB808700);国家自然科学基金(21232006)资助项目

会议文献：第十八届全国金属有机化学学术研讨会论文摘要集

会议名称：第十八届全国金属有机化学学术研讨会

会议日期：20140819

会议地点：中国甘肃兰州

主办单位：中国化学会

出版日期：20140819

学会名称：中国化学会

语　　种：中文

摘　　要：<正>During the past few decades,allene chemistry has experienced a great advancement,since they are very useful intermediates in organic synthesis.So far,different types of synthetic methods of functionalized allenes have been developed,~1 among which the allenylation of terminal alkynes(ATA)with aldehydes in the presence of amines and metal salts may be the most straightforward one.~2 Although many functional groups such as mesylate,ether,hydroxy,amide,etc.were tolerated under the current conditions,it is still interesting to apply this method for the synthesis of more

关 键 词：ATA  Mediated Synthesis of Carbohydrate-Based Allenes via ATA Reaction  

分 类 号：O627.12[化学类]