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期刊文章详细信息

甲基丙烯酸对纳米SiO_2微粒表面的原位聚合改性    

Surface Modification of Nano-SiO_2 by in-situ Polymerization of Methacrylic Acid

  

文献类型:期刊文章

作  者:沈新璋[1] 金名惠[1]

机构地区:[1]华中科技大学化学系,武汉430074

出  处:《应用化学》

基  金:华中科技大学研究生科技创新基金资助项目 (YCJ 0 2 0 0 8)

年  份:2003

卷  号:20

期  号:10

起止页码:1003-1005

语  种:中文

收录情况:AJ、BDHX、BDHX2000、CAS、CSCD、CSCD2011_2012、JST、RSC、ZGKJHX、核心刊

摘  要:Silane coupling agent was used to introduce polymerizable groups onto the surface of nano-SiO 2 particles. Then in-situ polymerization was carried out between the functionalized particles and methacrylic acid monmer to accomplish the surface modification of nano-SiO 2. Analysis of FTIR?TEM and TGA results show that methacrylic acid is grafted onto the surface of functionalized particles and the modified particles were stable. Contact angle measurement demonstrated that the modified particles were wetted by toluene completely and the contact angle with water was 105 ℃, indicating that the hydrophilic surface has been transfered to hydrophobic via the modification.

关 键 词:纳米SIO2 表面改性 甲基丙烯酸 硅烷偶联剂

分 类 号:O631]

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