文献类型：期刊文章

作　　者：卢圆圆[1] 刘果[1] 张静[1] 冯兆池[2] 李灿[2] 李智[3]

机构地区：[1]辽宁石油化工大学化学化工与环境学部化学与材料科学学院,辽宁抚顺113001 [2]中国科学院大连化学物理研究所催化基础国家重点实验室,辽宁大连116023 [3]中国科学院北京理化技术研究所光化学转换与光电材料重点实验室,北京100190

出　　处：《Chinese Journal of Catalysis》

基　　金：supported by the National Natural Science Foundation of China (21573101);the Liaoning Provincial Natural Science Foundation(2014020107);the Program for Liaoning Excellent Talents in University (LJQ2014041);the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry ([2013]1792);the Opening Project of Key Laboratory of Photochemical Conversion and Optoelectronic Materials, TIPC, CAS,the Opening Project of State Key Laboratory of Catalysis, DICP, CAS (N-09-06)~~

年　　份：2016

卷　　号：37

期　　号：3

起止页码：349-358

语　　种：中文

收录情况：AJ、BDHX、BDHX2014、CAS、CSA、CSA-PROQEUST、CSCD、CSCD2015_2016、EI(收录号：20161102099144)、JST、RSC、SCI(收录号：WOS:000372214000003)、SCI-EXPANDED(收录号：WOS:000372214000003)、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：A series of WO3 samples with different crystalline phases were prepared by the thermal decomposition method from ammonium tungstate hydrate.X-ray diffraction（XRD）,scanning electron microscopy（SEM）,high-resolution transmission electron microscopy（HRTEM）,X-ray photoelectron spectroscopy,and N2 adsorption-desorption were used to characterize the crystalline phase,morphology,particle size,chemical composition,and surface area of the WO3 samples.The formation of hexagonal（h-WO3） and monoclinic（m-WO3） crystal structures of WO3 at different temperatures or different times was confirmed by XRD.m-WO3 is formed at 600 ℃,while m-WO3 starts to transform into h-WO3 at 800℃.However,h-WO3,which forms at 800℃,may transform into m-WO3 by increasing the calcination temperature to 1000℃.SEM results indicate that m-WO3 particles exhibit a bulky shape with heavy aggregates,while h-WO3 particles exhibit a rod-like shape.Moreover,m-WO3 crystals are sporadically patched on the surface of the h-WO3 rod-like particles,resulting in the exposure of both m-WO3 and h-WO3 on the surface.It is observed that the monoclinic phase（m-WO3）/hexagonal phase（h-WO3） junction was fabricated by tuning the calcination temperature and calcination time.The relative ratios between m-WO3 and h-WO3 in the phase junction can readily be tailored by control of the calcination time.The photocatalytic activities of WO3 with different crystalline phases were evaluated by the photocatalytic degradation of rhodamine B as a model pollutant.A higher photocatalytic activity was observed in the WO3 sample with the m-WO3/h-WO3junction as compared with the sample with only m-WO3.The improvement of photocatalytic activity can be attributed to the reduction of the electron-hole recombination rate owing to the formation of the phase junction,whose presence has been confirmed by HRTEM and photoluminescence spectra.

关 键 词：Tungsten oxide  Phase junction  Thermal decomposition method  PHOTOCATALYSIS Rhodamine B  

分 类 号：O643.36]