文献类型：期刊文章

作　　者：张淑华[1] 蒋毅民[1]

机构地区：[1]广西师范大学化学化工系,桂林541004

出　　处：《无机化学学报》

年　　份：2002

卷　　号：18

期　　号：5

起止页码：497-500

语　　种：中文

收录情况：BDHX、BDHX2000、CAS、CSCD、CSCD2011_2012、IC、JST、RCCSE、RSC、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：The title complex was synthesized by reaction of taurine salicylic schiff base(TSSB), O phenanthroline(phen) and cupric acetate in water ethanol solution. The crystal structure was determined by X ray diffraction method and the chemical formula weight of the complex is 498.00. And the crystal structure belongs to orthorhombic system with space group Pbcn and cell parameters: a=31.072(4)?, b=12.8909(18)?, c=10.3478(14)?; V=4144.7(10)?3,Z=8,Dc=1.596Mg·m-3,μ=1.197mm-1 and F(000)=2048. The compound is an one dimensional chain complex of infinite length connecting with hydrogen bonds. The Cu? was coordinated by two oxygen atoms and three nitrogen while the O atoms of Ac groups did not coordinate. At the same time the Cu?formed a distorted tragonal cone. Besides the capacities of coordination to Cu? of atoms were discussed.

关 键 词：铜配合物 牛磺酸缩水杨醛席夫碱  晶体结构 合成  邻菲咯啉 三元配合物

分 类 号：O614.121]