文献类型：期刊文章

作　　者：乔庆东[1] 李琪[1] 于大勇[1] 梁红玉[1]

机构地区：[1]抚顺石油学院应用化学系,抚顺113001

出　　处：《应用化学》

基　　金：辽宁省自然科学基金!资助项目 (96 2 0 2 9)

年　　份：2000

卷　　号：17

期　　号：5

起止页码：555-557

语　　种：中文

收录情况：AJ、BDHX、BDHX1996、CAS、CSCD、CSCD2011_2012、JST、RSC、ZGKJHX、核心刊

摘　　要：The Ti-supported lead dioxide electrode（Ti/PdO2） consisted of a Sb2O3/SnO2 semiconductive interlayer and electrodeposited PbO2 films was prepared. The optimum ratio of Sb2O3 to SnO2 was 15%25%. Addition of NaF（0.40 g/L） in electroplating solution could decrease the rate of PbO2 deposition, which resulted in the formation of small crystal particles and compact PbO2 films. XRD study showed the β-form crystal of electrode. The electrode was tested in synthesis of 4-picoline acid by electro-oxidation of 4-picoline, showing good electroconductivity and stable life.

关 键 词：钛基二氧化铅电极  制备  电氧化反应  甲基吡啶

分 类 号：O646.5] O626.32[化学类]