文献类型：期刊文章

作　　者：王祥[1] 罗芳[2] 高文涛[1]

机构地区：[1]渤海大学超精细化学品研究所,锦州121000 [2]东北师范大学教育部多酸重点实验室,长春130024

出　　处：《无机化学学报》

基　　金：锦州市科技局计划项目(No.200317)

年　　份：2009

卷　　号：25

期　　号：1

起止页码：154-157

语　　种：中文

收录情况：BDHX、BDHX2008、CAS、CSCD、CSCD2011_2012、IC、JST、RCCSE、RSC、SCI(收录号：WOS:000262882200027)、SCI-EXPANDED(收录号：WOS:000262882200027)、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：A new 2D Hydrogen-bonded network complex [Ni(en)2(dpas)2] (Nadpas=sodium diphenylamine sulphonic acid salt,en=ethanediamine) has been synthesized in aqueous solution,and characterized by elemental analysis,IR. The crystal structure was determined by single-crystal X-ray diffraction. The complex crystallizes in space group P21/c,with cell parameters a=0.605 6(5)nm,b=1.448 1(5) nm,c=1.711 9(5)nm,β=93.257(5)°,and V=1.498 9(14) nm3,Dc=1.497 g·cm-3,Z=2,F (000)=708,R=0.027 7,wR=0.072 5. The crystal structure shows that the nickel atom is coordinated with four nitrogen atoms from the two en and two oxygen atoms from two dpas to form a mononuclear complex. Furthermore,the adjacent complex units are extended into a 2D supramolecular network through hydrogen bonds.

关 键 词：镍(Ⅱ)配合物  氢键 晶体结构 电化学性质

分 类 号：O614.813]