文献类型：期刊文章

作　　者：张裕平[1] 左国强[2] 许光日[1] 李全民[2] 袁倬斌[1]

机构地区：[1]河南科技学院应用化学研究所,新乡453003 [2]河南师范大学化学系,新乡453007

出　　处：《高等学校化学学报》

基　　金：中韩国际合作项目(批准号:20611140646);河南省高校新世纪优秀人才基金(批准号:2006HNCET-01);高等学校骨干教师基金资助.

年　　份：2007

卷　　号：28

期　　号：9

起止页码：1654-1656

语　　种：中文

收录情况：AJ、BDHX、BDHX2004、CAS、CSCD、CSCD2011_2012、EI(收录号：20074610916238)、IC、JST、RCCSE、RSC、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：Microwave irradiation was firstly attempted to prepare molecularly imprinted polymers(MIPs)monoliths,which were in situ prepared rapidly with methacrylic acid(MAA)as a functional monomer,ethylene glycol dimethacrylate(EDMA)as a cross-linking agent,toluene and isooctane as the porogenic solvents and AIBN as an initiator.The baseline separation of isomers of hydroxybenzoic acid was achieved on these monolithic columns with 4-HBA as the template,but not on the blank polymer.Furthermore,some neutral compounds could also be baseline-separated on the imprinted polymer columns in the modes of pressure-driven capillary electrochromatography and low-pressure driven capillary electrochromatography.It was shown that the monoliths were not only used as the molecularly imprinted polymers but also as the reverse phase chromatographic material.

关 键 词：微波 分子印迹聚合物 整体柱 毛细管电色谱

分 类 号：O657]