文献类型：期刊文章

作　　者：杨健国[1] 潘富友[2] 李钧敏[2]

机构地区：[1]台州学院设备管理处,台州317000 [2]台州学院生命科学与医药化工学院,台州317000

出　　处：《无机化学学报》

基　　金：浙江省自然科学基金资助项目(No.M203115);浙江省教育厅科研资助项目(No.20050057)

年　　份：2005

卷　　号：21

期　　号：10

起止页码：1593-1596

语　　种：中文

收录情况：BDHX、BDHX2004、CAS、CSCD、CSCD2011_2012、IC、JST、RCCSE、RSC、SCI-EXPANDED(收录号：WOS:000232613600031)、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：In ethanol, the copper(II) complex with the 2′-(2-thienylidene)-h ydroxybenzoylhydrazide, Cu(C12H10N2O2S)2, was synthesized, and it′s structure was characterized by IR, UV and elemental analysis. The single crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group C2/c with cell constants, a=2.273 6(4) nm, b=0.592 12(9) nm, c=1.828 1(3) nm, β=109.735(5)°, V=2.316 4(7) nm3, Z=4, μ=1.164 mm-1, Dc=1.595 g·cm-3, F(000)=1 140, R=0.048 6, wR=0.101 6. In the compound copper(II) atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. Their biological activities have been measused. The results show that the anti-bacterial activity of the coordination compound is much better that of the ligand. CCDC: 272938.

关 键 词：铜配合物 2'-(2-噻吩亚甲基)水杨酰腙  晶体结构 抑菌活性  

分 类 号：O614.121]