文献类型：期刊文章

作　　者：朱龙章[1] 刘淑兰[2] 覃奇贤[2] 郭鹤桐[2]

机构地区：[1]上海技术师范学院,上海201418 [2]天津大学应用化学系,天津300072

出　　处：《物理化学学报》

基　　金：国家自然科学基金

年　　份：1994

卷　　号：10

期　　号：11

起止页码：1055-1058

语　　种：中文

收录情况：AJ、BDHX、BDHX1992、CAS、CSCD、CSCD2011_2012、EBSCO、IC、INSPEC、JST、PUBMED、RCCSE、RSC、SCI-EXPANDED(收录号：WOS:000207589800018)、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：Ni-WC composite coating was obtained by using composite electrodeposition technique. The behavior of Ni-WC composite coating used as cathode material for hydro gen evolution reaction (HER) in a medium of 0.1 mol .L-1H2SO4+0.5mol.L-1 Na2SO4 was inverstigated. The experimental results show that the catalytic activity of Ni-WC composite electrode for HER in weak acidic medium is appearently higher than that of the electrode plated with Ni and is increased with the increasing of WC content in the coating. As compared with Ni plated electrode, the increase in catalytic activity of the composite electrode for HER should be attributed to the dispersion of WC particles in the Ni deposit, since the mechanism of HER for the two kinds of electrodes is the same.Owing to the incorporation of WC particles in Ni deposit, the standard activation free enthalpy for HER is decreased, and the defects and dislocations in the crystal sturcture of the composite coating are increased. This is equivalent to the addition of catalysis accelerator WC in the catalyst Ni.

关 键 词：镍复合电极  酸性介质 催化析氢反应  

分 类 号：O646.5]