文献类型：期刊文章

作　　者：建方方[1] 肖海连[1] 孙萍萍[1]

机构地区：[1]青岛科技大学新材料与功能配合物实验室,青岛266042

出　　处：《无机化学学报》

基　　金：山东省自然科学基金(No.Y2002B06);青岛科技大学科研基金(No.03Z08)

年　　份：2004

卷　　号：20

期　　号：11

起止页码：1339-1343

语　　种：中文

收录情况：BDHX、BDHX2000、CAS、CSCD、CSCD2011_2012、IC、JST、RCCSE、RSC、SCIE、SCOPUS、WOS、ZGKJHX、核心刊

摘　　要：The title compound, [CoCl2(C7H5N2CH2Ph)2], has been synthesized and structurally characterized by elemental analysis, IR, UV-Vis spectra, TG-DSC and X-ray crystallography. The coordination geometry of each Co atom is formed, by two N atoms from two benzyl-benzimidazole ligands and by two Cl anions, is of a tetrahedron. The data of EA, IR and UV-vis spectra are in good agreement with the result of crystal structure determination. The thermal gravimetry (TG) data indicate that there are four decomposition steps with five endothermic peaks. The final product of the thermal decomposition is Co. The electrochemical properties of the complex was also studied in H2O/DMF solvent by cyclic voltammetry(CV). CCDC:211442.

关 键 词：1N-苄基-苯并咪唑配体  钴配合物 晶体结构 电化学 热稳定性  

分 类 号：O614.812] O641.4[化学类]